SYNTHESIS N-PHENYLAMINEDITHIOCARBAMATE AS CHELATING AGENT IN SOLVENT EXTRACTION
ABSTRAK: Dithiocarbamate
derivatives is a versatile ligand that contain two atoms of sulfur as a strong
electron donor. It combines with metals. N-phenylaminedithiocarbamate has
synthesized and applied in solvent exctration. Synthesis carried out with
addition carbon disulphide to N-phenylamine and concentrated pottasium
hydroxyde in metanol. The result was characterized by spectroscopy 1H-NMR,
13C-NMR, FTIR, Elemental Analysis, that showed molecular structure was
significant. Applied N-Phenylaminedithiocarbamate in solvent extraction showed
precent of result Cu(II), Co(II), Cr(III) and Ni (II) were 90.45% - 99.99% at
pH 4-9.
Penulis: Soja Siti Fatimah,
Vera Musfiroh, Zackiyah Zackiyah, Husein H. Bahti, Iwan Hastiawan, Anna
Permanasari
Kode Jurnal: jpkimiadd140908
